2-Amino-5-methylpyridinium 2-aminobenzoate
نویسندگان
چکیده
In the title compound, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (-), the H atom of the N-H group and an H atom of the 2-amino group from the cation are involved in inter-molecular N-H⋯O hydrogen bonds with the O atoms of the carboxyl-ate group of the anion, forming an R(2) (2)(8) ring motif. These ring motifs are, in turn, connected by further N-H⋯O hydrogen bonds, forming a two-dimensional network. The crystal structure is further stabilized by π⋯π stacking inter-actions involving the benzene and pyridinium rings with a centroid-centroid distance of 3.7594 (8) Å.
منابع مشابه
2-Amino-4-methylpyridinium 4-aminobenzoate
In the structure of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (-), the 4-amino-benzoate anions are linked to adjacent anions and 2-amino-4-methyl-pyridinium cations via N-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular structure. The crystal structure also shows a weak C-H⋯O hydrogen bond between adjacent anions. Within the 4-amino-benzoate anion, the carboxyl-ate group is ...
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